1、吉林化工学院 成人教育学院 毕业设计外文翻译 8000 吨 /年醋酐装置精馏工段工艺设计 学生学号 09360106 学生姓名 刘雪婷 专业班级 111 化学工程与工艺 指导教师 丁斌 教授 完成日期 2011.09.03 吉林化工学院 JilinInstituteofChemicalTechnology 化工与材料工程学院毕业设计（论文）外文翻译 - 1 - Acetic anhydride production process Acetic anhydride is a colorless volatile, with a strong irritating smell and corro
2、siveness liquid. Name of acetic anhydride, molecular formula C4H6O3, the flash point of 64.4 DEG c. Density of 1.082 0g / cm3. Melting point - 74.13 DEG c. The boiling point of 138.63 DEG c. The refractive index nD 1.390. 20 degrees of viscosity of 0.91 mPa? S. Spontaneous ignition temperature of 38
3、8.9 DEG c. Soluble in cold water, in water is decomposed into acetic acid, ethyl acetate and ethanol production. Soluble in chloroform, ether and benzene. Toxic, eye and mucosa has a strong irritating, mass concentration of 0.36 mg / m3 when the eye irritation； 0.18mg / m3, can change a persons brai
4、n electrical image, can cause tissue protein modification. The steam stimulation is stronger, extremely easy to burn the skin and eyes, such as frequent exposure can cause dermatitis and chronic conjunctivitis. On rat oral LD50 was 1780 mg / kg. When spilled and or adhesion to the skin, to immediate
5、ly with water or 2% washing soda, systemic poisoning should be timely medical treatment. Air max allowable volume fraction 5 u L / L. Acetic anhydride is the country to encourage the development of basic organic chemical raw materials, mainly used for the production of cellulose acetate, of which tw
6、o cellulose acetate is used in the manufacture of cigarette filter tip and plastic, three cellulose acetate is the manufacturing of advanced film material, is widely used in medicine, pesticides, dyes, military, spices, metal finishing industries.Acetic anhydride is precursor products, acetic anhydr
7、ide production, management must be in the public security organ for archival filing certification, enterprises sold every batch of goods to perform detailed registration, and to the public security organ for the record. According to the legal provisions, to undocumented units 200 kg acetic anhydride
8、, will be sentenced to 3 years imprisonment. Industrialization of acetic anhydride production process has three kinds: the oxidation of acetaldehyde, ethylene ketone and methyl acetate carbonylation. Acetaldehyde oxidation technology source for the Canadian Sha Winigan chemical company. The producti
9、on process is as follows: acetaldehyde and oxygen at 60 degrees C, 101 kPa or 70 degrees C, 600-700kPa under the conditions of the oxidation reaction, oxygen or air as the oxidant, using ethyl acetate as solvent, cobalt acetate as catalyst, acetic acid copper as promoter. Acetaldehyde and oxygen ( i
10、n excess of about 1%-2%) reaction is first generated peroxy acetic acid, acetic acid and acetaldehyde reaction of acetic anhydride and acetic acid. Under this condition, the conversion rate of acetaldehyde acetic anhydride and acetic acid production rate is 95%, the mass ratio of 56: 44. The total y
11、ield of 70%-75% acetic anhydride. By changing the processing conditions, can improve the yield of acetic anhydride. Reaction equation: CH3CHO+O2 - CH3COOOH； 化工与材料工程学院毕业设计（论文）外文翻译 - 2 - CH3COOOH+CH3CHO CH3COOOCH ( OH ) CH3 ( single peroxy acetic ester )； CH3COOOCH ( OH ) CH3 - ( CH3CO ) 2O+H2O； CH3CO
12、OOCH ( OH CH3 2CH3COOH ). Acetaldehyde acetic anhydride consumption per ton of 1.165 T, 2300 m3 standard air. Acetaldehyde oxidation method has the advantages of simple process, technology is mature, but the serious corrosion, high consumption, has gradually been eliminated. In foreign countries hav
13、e been carbonylation of methyl acetate and vinyl ketone method alternative. China Shanghai Chemical Reagent Factory of this device has been in a state of production. Vinyl ketone law in accordance with the different materials can be divided into: acetic acid and acetone method. Acetic acid process t
14、echnology from Germany Wacher chemical company. The production process is as follows: in the first step, the acetic acid in 700-750 C, 10-20kPa pressure and 0.2%-0.3% phosphoric acid three ethyl ester (by acetic acid quality plan) as catalyst under the conditions of dehydration, cracking ethylene ke
15、tone acetate made, conversion rate is about 85%-90%, on vinyl ketone selectivity (corporeal quantity meter ) is about 90%-95%. Reaction equation: CH3COOH CH2 = C = O+H2O+147 kJ / mol. The second step is to absorb liquid acetic acid ethylene ketone anhydride generating, by distillation and purificati
16、on to obtain the product of acetic anhydride, vinyl ketone conversion rate of about 100%. Reaction equation: CH3COOH+CH2 = C = O ( CH3CO ) 2O+62.8kJ / mol. The production process is a German Wacher chemical company to develop a success, and in 1936 achieved industrialization. Two existing production
17、 process: One, as the tower process. Using 4 packed tower for synthesis and separation. The consumption of per ton of acetic anhydride as catalyst, acetic acid 1.35t, 1.5-2kg 0.7-1.0kg 100-160kg, ammonia, acetic acid recovery. Secondly, as the liquid ring pump flow. The liquid ring pump for reaction and absorption equipment. The process is simple, being replaced by tower process. Per ton of products consumption quota for acetic acid cracking rate, 1.22 T, 75%, the yield of synthesis of 96%. The production process is as follows:
